One-pot synthesis of core-expanded naphthalene diimides: enabling N-substituent modulation for diverse n-type organic materials.

نویسندگان

  • Yunbin Hu
  • Yunke Qin
  • Xike Gao
  • Fengjiao Zhang
  • Chong-an Di
  • Zheng Zhao
  • Hongxiang Li
  • Daoben Zhu
چکیده

A mild and versatile one-pot synthesis of core-expanded naphthalene diimides has been developed, which undergoes a nucleophilic aromatic substitution reaction and then an imidization reaction, allowing an easy and low-cost access to diverse n-type organic materials. Some newly synthesized compounds by this one-pot operation exhibited high electron mobility of up to 0.70 cm(2) V(-1) s(-1) in ambient conditions.

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عنوان ژورنال:
  • Organic letters

دوره 14 1  شماره 

صفحات  -

تاریخ انتشار 2012